WOOD RESEARCH Volume 61, Number 5, 2016
Zuzana Brezániová, Mária Fišerová, Monika Stankovská, Juraj Gigac, Elena Opálená, and Jarmila Puškelová

Effect of prehydrolysis on enzymatic hydrolysis of two-stage pretreated wheat straw

The effect of water prehydrolysis conditions, which was used as the first stage of wheat straw pretreatment, on the composition of filtrates was analysed. Many of the substances that are present in the prehydrolysis filtrates are broadly used and thus they contribute to improvements in the efficiency of bioethanol production. Prehydrolysis was carried out at temperatures of 140, 160 and 180°C and times of 30, 60 and 120 min. Xylose and its oligomers were the most represented in prehydrolysis filtrates, their yields increased up to 12.1 % with increasing weight of wheat straw removed up to 28.6 %. Besides xylose and glucose, acetic acid, formic acid and the phenolic compounds were also present in the prehydrolysis filtrates. At 160 and 180°C, levulinic acid and furfural and hydroxymethylfurfural, respectively, were also present. The solid fractions of wheat straw were subjected to steam explosion under the same conditions at 200°C for 2 min. Two-stage pretreated wheat straw was subsequently enzymatically hydrolysed. The conditions of water prehydrolysis combined with steam explosion pretreatment had a significant effect on the results of enzymatic hydrolysis of wheat straw. The conversion of cellulose increased with increasing prehydrolysis temperature and time from 64.8 to 91.7 %. Similar results were observed for the conversion of xylan from 73.7 to 92.4 %. With increasing of prehydrolysis temperature and time, the amount of inhibitors in hydrolysates decreased. The recommended conditions for water prehydrolysis at two-stage pretreatment of wheat straw correspond to temperature of 160°C and time of 60 min.

WOOD RESEARCH Volume 61, Number 5, 2016
Kuňa Vladimír, Balberčák Jozef, Elena Opálená, Pažitný Andrej, Albert Russ, and Jiří Schwartz

The effect of multi-component retention systems on the properties of the paper suspensions

This study presents the influence of retention reagents and multi-component retention systems on properties of pulp suspension which is used during toilet paper production. The following relationships were evaluated: influence of retention systems on rate of pulp suspension water drainage, values of specific cationic and anionic demand, Zeta potential of fibers, WRV values of fibers and water turbidity. The best results were achieved from applying three-component retention system which consisted of micro-milled bentonite Hydrocol OT, modified cationic polyethylenimin Polymín SK and cationic polyacrylamide Percol 830. The above mentioned three-component retention system resulted in increased rate of pulp suspension drainage by 43 %, improvement of water turbidity by 50 % and decrease of specific cationic demand by 33 %. The proposed retention system resulted in improved values of WRV pulp suspensions, which led to decrease of values by about 10 %. Influence of three-component retention system resulted only in minimal decrease of Zeta potential values for fibers.

WOOD RESEARCH Volume 61, Number 2, 2016
Juraj Gigac, Monika Stankovská, Elena Opálená, and Pažitný Andrej

The effect of pigments and binders on inkjet print quality

The effect of silica and calcium carbonate pigments, polyvinyl alcohol and cationic starch binders combined with high-cationic polymers on physical-chemical and printing properties of coated papers were studied. The best printing properties were obtained with coating colour based on silica. Colour gamut significantly improved when the inkjet ink contact angle decreased below 15°. The water fastness was influenced with specific charge density of coating colour. Application of silica provided papers with the largest inkjet ink wetting, colour gamut area, print sharpness and surface roughness. By using of polyvinyl alcohol a high colour gamut area was reached but it resulted in a low print sharpness in comparison with cationic starch. High-cationic polymer poly-DADMAC showed a more significant effect on all printing properties of coated paper in comparison with SMAI 1000. The final inkjet print quality depends on structural and chemical properties of coating.

WOOD RESEARCH Volume 61, Number 1, 2016
Albert Russ, Mária Fišerová, Michal Letko, and Elena Opálená

Effect of steam explosion temperature on wheat straw enzymatic hydrolysis

Wheat straw is an abundant and readily available lignocellulosic material potentially suitable for the second generation bioethanol production. Steam explosion was investigated as a suitable pretreatment method. Effect of steam explosion temperature on wheat straw enzymatic hydrolysis was investigated. Optimum steam explosion temperature at around 200°C was determined based on concentration of monosaccharides in hydrolysates, conversion of cellulose and xylan and yield of monosaccharides from wheat straw. This corresponds to creating conditions resulting in sufficient damage to the lignocellulose structure which leads to higher enzyme accessibility. Lower temperature does not enable sufficient enzyme accessibility while excessively high temperature results in significant breakdown of monosaccharides and lignin and creation of inhibitors. The amount of originated inhibitors was also determined for each studied steam explosion temperature.

WOOD RESEARCH Volume 63, Number 4, 2018
Mária Fišerová, Elena Opálená, Juraj Gigac, and Monika Stankovská

Oxidative and reductive bleaching of deinked pulp

Deinked pulps for hygienic paper production were bleached with hydrogen peroxide and sodium dithionite in single and two-stage bleaching. The brightness gain of high brightness deinked pulp in the peroxide stage was 5.7% ISO and of low brightness 4.4% ISO. In sodium dithionite stage, the brightness gain of high brightness deinked pulp was 4.0% ISO and of low brightness deinked pulp 3.8% ISO. The two-stage oxidative-reductive bleaching sequence resulted in an increase of brightness by 9.7% ISO for high brightness deinked pulp and by 9.1% ISO for low brightness deinked pulp. Brightness gain in the two-stage reductive-oxidative bleaching sequence was 6.7% ISO for high brightness deinked pulp and 5.6% ISO for low brightness deinked pulp. The coordinate b* value and yellowness of deinked pulps decreased in sodium dithionite bleaching stage more than in hydrogen peroxide stage. The two-stage oxidative-reductive bleaching sequence is more preferred than reductive-oxidative sequence regardless of the fibre composition. The tensile index and the tensile energy absorption index of deinked pulps slightly decreased after single-stage and two-stage bleaching sequences, their reduction in the peroxide stage was greater than in the dithionite stage. The fibre strength and fibre length characteristics of deinked pulps decreased after bleaching, while fibre bonding ability increased. The water absorption and bulk softness increased after bleaching, the increase was higher after peroxide stage than dithionite stage.

WOOD RESEARCH Volume 65, Number 3, 2020
Monika Stankovská, Mária Fišerová, Juraj Gigac, and Elena Opálená

Blending impact of hardwood pulps with softwood pulp on tissue paper properties

The influence of proportions of bleached birch, eucalyptus, beech kraft pulps as well as the bleached aspen chemi-thermomechanical pulp (BCTMP) in the mixture with bleached pine kraft pulp on tissue paper properties was compared. Increase of bleached beech kraft pulp and aspen BCTMP proportion in a mixture with bleached pine kraft pulp leads to significant rise of porosity ε as well as bulk. The water absorption after immersion increased significantly with increase of aspen BCTMP content in the mixture while other hardwood pulps in the mixture had only moderate impact. Increasing of bleached beech and eucalyptus kraft pulps content in the mixture continually increased initial water absorption. As a result of blending of bleached birch kraft pulp with bleached pine kraft pulp, bulk softness improved and the tensile index increased slightly. The increased content of bleached birch and beech kraft pulp in the mixture increased the brightness while the addition of aspen BCTMP and bleached eucalyptus kraft pulp increased of coordinate b* value. Mixed pulps with properties suitable for different types of hygienic products were selected.

WOOD RESEARCH Volume 64, Number 2, 2019
Monika Stankovská, Juraj Gigac, Mária Fišerová, and Elena Opálená

Relationship between structural parameters and water absorption of bleached softwood and hardwood kraft pulps

The influence of porosity, relative bonded area and air permeability on water absorption of unbeaten and beaten bleached kraft pulps from different wood species used for tissue paper production was investigated. The water absorption was determined by four different methods such as absorption of water after immersion, initial water absorption, water absorption capacity and saturation rate with water. Linear dependences between water absorption parameters and the structural parameters of individual pulps as well as all tested pulps were obtained. The correlation coefficients obtained within individual bleached kraft pulps were from 0.95 to 1.00 and within the whole group of pulps were from 0.86 to 0.98. Relative bonded area and air permeability were found to be the most suitable parameters for predicting of initial water absorption and saturation rate with water.

WOOD RESEARCH Volume 66, Number 3, 2021
Monika Stankovská, Mária Fišerová, Juraj Gigac, and Elena Opálená

Effect of addition of deinked pulp to bleached kraft pulp on tissue paper properties

The influence of addition of deinked pulps with low and high brightness to bleached eucalyptus and pine kraft pulps on functional tissue paper properties was studied. Deinked pulps with low and high brightness had some different functional properties. Deinked pulp with high brightness has higher bulk, porosity, water absorption after immersion, initial water absorption, bulk softness as well as brightness. On the contrary, the difference in relative bonded area and porosity e between deinked pulps with low and high brightness was moderate. The mixed pulps laboratory pulp sheets from bleached eucalyptus kraft pulp or bleached pine kraft pulp with addition of 20, 40 and 80% of deinked pulp with low brightness or deinked pulp with high brightness were prepared. The addition of the deinked pulp with high or low brightness to bleached kraft pulp leads to increasing of bulk, bulk softness as well as high water absorption after immersion and initial water absorption. The tensile index rapidly decreased by the addition of deinked pulps with high brightness to bleached eucalyptus and pine kraft pulps. Similarly, the addition of deinked pulp with low brightness to bleached pine kraft pulp led to rapid decreasing of tensile index. On contrary, with the addition of deinked pulp with low brightness to eucalyptus kraft pulp, the decreasing of tensile index was less pronounced. Mixed pulp from bleached eucalyptus kraft pulp with a small content of deinked pulp with low brightness with functional properties suitable for production of tissue papers was found as optimal.