Development of bonding strength of modified birch veneers during adhesive curing

This study investigated the bonding strength development of furfurylated, N-methylol melamine (NMM) modified and thermally treated birch veneers glued with hot curing phenol formaldehyde (PF) adhesive in different pressing (20, 160 s) and open assembly times (20 s, 10 min). For testing, the automated bonding evaluation system ABES was used with 2 N.mm-2 applied pressure at 130°C. The bonding strength of both modified and unmodified samples increased significantly by prolongation of the pressing time from 20 to 160 s in all cases and for both open assembly times. A deviation was observed for the samples treated at 220°C and at 20 s open assembly time. With the exception of NMM modified veneers, bonding strength did not change significantly by increasing the assembly time in the case of 20 s pressing for both modified and unmodified samples. At 160 s pressing time, extension of the assembly time developed a better bonding for controls, NMM modified and thermally treated veneers at 180°C. The combination of 10 min assembly time and 160 s pressing time proved as the optimal bonding condition for controls, NMM modified and thermally treated veneers at 180°C while the highest bonding strength was noted in 20 assembly time and 160 s pressing time for furfurylated veneers. In most of the cases modification affected negatively the bonding performance of the veneers, in particular for furfurylated and NMM modified samples.

Resonance and time-of-flight methods for evaluating the modulus of elasticity of particleboards at different humid conditions

Non-destructive testing of wood panels by either resonance or time-of-flight (TOF) methods provides possibilities for predicting their static bending properties. In the present study, three non-destructive devices (BING – Beam Identification by Non-destructive Grading by CIRAD, Montpellier, France, Fakopp Ultrasonic Timer and Sylvatest TRIO) were used for measuring the dynamic stiffness of different particleboard types. Fakopp Ultrasonic Timer and Sylvatest TRIO produce ultrasonic pulses to measure the sound velocity while BING uses resonance frequencies. Commercially produced particleboards with different thickness and densities were used to measure the dynamic modulus of elasticity (MOEdyn) in two directions (parallel and perpendicular to the production line) and at three different humidity levels (dry – 35%, standard – 65% and wet – 85% RH in constant temperature of 20°C ). MOEdyn of particleboards were correlated with the static moduli of elasticity (MOEstat) and rupture (MORstat). It was found that the non-destructive methods gave higher MOEdyn values in both production directions than that of MOEstat values. MOEdyn was found to decrease from dry to wet conditions. A very strong and statistically significant correlation existed between MOEdyn and static bending properties. MOEdyn correlated stronger to MOEstat than MORstat. At different humidity level, all three methods- Fakopp Ultrasonic Timer, BING and Sylvatest TRIO analyses showed good predicting capabilities to estimate MOEstat and MORstat of different particleboard types with high level of accuracy.

Shear strength of heat-treated solid wood bonded with polyvinyl-acetate reinforced by nanowollastonite

This study investigated the shear strength of heat-treated solid wood of three species (beech, poplar, and fir) bonded with polyvinyl-acetate (PVA) adhesive reinforced by nanowollastonite (NW). Wood specimens were heat-treated at 165°C and 185°C, and then bonded using PVA reinforced by 5% and 10% of NW. Shear strength tests parallel to the grain of bonded specimens were performed according to ASTM D143-14 (2014). The results demonstrated that the shear strength was significantly dependent upon the density of the specimens. Heat treatment decreased the shear strength of the bonded specimens considerably. This was attributed to several factors, such as a reduction in polar groups in the cell wall, increased stiffness of the cell wall after heat treatment, and a reduction in the wettability of treated wood. However, NW acted as a reinforcement agent or extender in the complex, and eventually improved the shear bond strength. Moreover, the density functional theory (DFT) proved the bond formation between calcium atoms in the NW and hydroxyl groups of cell wall polymers. The overall results indicated the potential of NW to improve the bonding strength of heat-treated wood.

Properties of medium-density fibreboards bonded with dextrin-based wood adhesive

This study focuses on manufacturing of medium density fibreboard (MDF) panels bonded with dextrin-based wood adhesive and crosslinked in situ with various weight ratios of synthetic (e.g., polymeric-methane diphenyl-diisocyanate, pMDI) or bio-based (e.g., glyoxal) crosslinkers. The physical and mechanical properties of the panels were evaluated and compared with those from panels without crosslinker (control). Modulus of rupture (MOR) and internal bond (IB) strength of the MDF panels were considerably increased by increasing the crosslinkers’ content. While, slight improvements were observed in modulus of elasticity (MOE) of the panels as a function of crosslinker type and content. Addition of crosslinkers clearly reduced the thickness swelling (TS) and water absorption (WA) of the panels, whereas, the panels with pMDI showed superior performances than the control and glyoxal added ones within 4 h and 24 h immersion in water. The results indicate the potential of dextrin as wood panel adhesive along with the use of appropriate crosslinkers.