Discoloration of oak veneer induced by metal ions

The 3 mm thick oak veneers were discolored by single ions of Fe2+, Cu2+, and Mn2+ and mixed ions of Fe2+-Cu2+, Fe2+-Mn2+, and Cu2+-Mn2+. The brightness (L*), red-green index (a*), and yellow-blue index (b*) of the veneers changed by varying degrees with the changes in ion mass fraction, temperature, heating time, ion species, and ion mass fraction ratio. The maximum values of total color difference (△E*) of the veneers were 38.94, 11.79, and 9.42 for Fe2+, Cu2+, and Mn2+. Moreover, the total color difference (△E*) values of 24.07, 13.71, and 4.45 were observed for Fe2+-Cu2+, Fe2+-Mn2+, and Cu2+-Mn2+ mixed ions. The veneers showed different degrees of vibrational peaks after discoloration. According to the ultraviolet spectrum, Fe2+ had a red shift in the ultraviolet absorption band of the unsaturated carbonyl compound and benzene ring compound. Moreover, the dark effect of Fe2+, Fe2+-Cu2+, Fe2+-Mn2+, Mn2+, Cu2+-Mn2+, and Cu2+ gradually decreased. The surface of the veneer was flat, without any rupture or deformation, and the pores were clear after treatment.

Study of the discoloration behaviour of teak wood (Tectona grandis Linn. fil.) caused by simulated sunlight

To investigate the discoloration behaviour of teak (Tectona grandis Linn. fil.) during irradiation, teak veneer specimens were exposed to xenon lamp light simulating sunlight for 80 h and subsequently analysed with a colorimeter. The colour changes were explained by recording Fourier transform infrared (FTIR) and gas chromatography-mass spectrometry (GC-MS) spectra at different exposure times. Forty hours of simulated irradiation marked a key point in the colorimetric analysis. During irradiation of 40 h, the increase in the CIELAB parameters ∆a* and ∆b* originated from the generation of carbonyl derivatives that were determined by FTIR analysis. Besides that, by combining GC-MS and microscopic analyses, the decrease in ∆L* in the first 20 h resulted from extractives migrating from the interior to the surface, and that the subsequent increase in ∆L* mainly arose from volatilization of the extractives. Additionally, the decrease in ∆b* after another 40 h of irradiation was mainly due to decreasing volatile extractive contents. Our conclusion reveals the causes of photo-induced discoloration in teak.

A study on suitability of some wood species for landscape applications: Surface color, hardness and roughness changes at outdoor conditions

In this study, each of the commonly used two types of woods (softwood and hardwood) from five species was studied. All wood species show a systematic trend to change to higher values of surface roughness with natural weathering progress. The Black pine, Calabrian pine and beech wood samples show a more or less smooth trend, whereas basswood gives the highest surface roughness changes under all conditions. However, the hardwood species, except basswood, have higher hardness properties both initially and at the end of weathering process when compared to softwoods. The surface discoloration that occurs is clearly visible as a natural texturing. However, the degree of, and the pattern of texturing, may vary with different kinds of woods; the color changes also vary to some extent. It was revealed that the discoloration is strongly dependent on the botanical origin of wood species. The lower lightness changes (ΔL %) were found for all three pine species (16.2 to 37.2%) when compared to fir (54.9%) and spruce samples (91.8%). The Scotch pine wood showed highest values for the contribution of red color initially and low redness change on the surface after the weathering process, among the other softwood species.