Comparative study of wood color stability using accelerated weathering process and infrared spectroscopy

The objective of this study was to investigate effects of artificial weathering on color stability of six tropical wood species: Apuleia leiocarpa (Vog.) Macbride, Bagassa guianensis Aubl., Dipteryx odorata (Aubl.) Wild., Hymenea courbaril/Linn., Manilkara bidentata A. Chev., Tabebuia sp. Chemical composition of weathered wood was also studied by FT-IR spectra. With the progressive artificial weathering color of wood changed gradually. Hymenea courbaril Linn. wood occurred the greatest range of the total color change. The largest changes in intensity of the wood color took place at the beginning of artificial weathering process. FT-IR analysis indicated the occurrence of lignin and hemicellulose oxidative changes resulting in formation of carbonyl and carboxyl compounds during weathering. Oxidation products are the main cause of wood surface discoloration. Additionally, changes suggesting depolymerisation of cellulose were identified as well.

Development and validation of an analytical method for condensed tannin extracts obtained from the bark of four tree species using HPLC

Herein, we evaluated the content of condensed tannins present in the bark of four tree species that are Quercus laurina Humb. & Bonpl., Quercus crassifolia Humb. & Bonpl., Arbutus xalapensis Kunth, and Prunus serotina Ehrn. An analytical method using high-performance liquid chromatography (HPLC) for condensed tannin extracts was developed and validated. Also, the aqueous extracts were analyzed by Fourier transform infrared spectroscopy (FTIR). Based on the Stiasny number, A. xalapensis, and Q. laurina represent an important source of condensed tannins, which may be subject to exploitation. Using infrared spectroscopy, it was observed that tannins do not show an important signal of carbonyl groups (aromatic esters) with respect to high purity catechin. Furthermore, the band of the hydroxyl group is less pronounced in tannins, because various hydroxyl are interacting with each other. However, it can be seen that the method of extraction of wood tannins developed in this work, presents satisfactory results.