Improvement of oil and grease resistance of cellulosic materials

The oil and grease resistance of paper after surface sizing with aqueous dispersions composed of film forming polymers, their mixtures with fluorinated polymer or fluorinated polymer and silver nanoparticles was compared. The oil and grease resistance of paper was regulated by changing the composition and intake of aqueous dispersions and paper grade, and it was evaluated by the content of fine surface pores, contact angle, oil absorptiveness, grease resistance, oil repellency on the inclined surface and oil penetration time. The aqueous dispersions were applied on one side and on both sides of paper surface in the size press. The film forming polymer has created a physical barrier against oil and grease, while combination with the fluorinated polymer developed a physical and chemical barrier. The papers sized with aqueous dispersions containing a mixture of film forming and fluorinated polymer with the addition of silver nanoparticles, achieved high oil and grease resistance even with lower consumption of the fluorinated polymer, and also achieved an antimicrobial surface. The more porous paper has achieved the required oil and grease resistance at higher polymers intake.

Preparation The Rose-like hydrophobic surface of wood based materials by soft lithography

To prepare hydrophobic wood with rose-like hydrophobic surface and avoid moisture damage to wood. In this paper, With polyvinyl alcohol (PVA) as the elastic mold, the microstructure of the rose petals was replicated on the wood surfaces by soft lithography. The soft lithography technique was used to modify the wood sur-face, transferring over it a rose-like topography, based on a micro/nano hierarchical structure using fresh rose as the template. The surface of poplar coated with polystyrene was reconstructed twice using 1, 3, 5, 8 and 10% PVA as templates, respectively. The results show that the average contact angle of poplar surface coated with polystyrene is more than 130°, that of fresh rose surface is about 140°, and that of untreated wood is about 60°. Therefore, the wood surface with polystyrene has obtained a similar structure to that of rose surface and has a certain hydrophobicity. In addition, the microstructures observed by means of SEM, showing rough surface structures with micro-nanopapillate hills on wood surfaces. Water droplets could easily roll down on such wood surfaces, exhibiting super-hydrophobic and low adhesion properties. The successful fabrication of rose-like wood provided a new direction for researches on the super-hydrophobic of wood, which could effectively prevent the damage of moisture to wood.