THE EFFECT OF COMPOSITE MODIFIED BORON-BASED WATERBORNE FLAME-RETARDANT COATING ON COMBUSTION PERFORMANCE OF BAMBOO DECORATIVE FILAMENT

To address the flammability of bamboo decorative filament, seven waterborne composite flame-retardant coating systems were developed using waterborne acrylic resin as the film-forming matrix, with boric acid, borax, ammonium polyphosphate (APP), nano-SiO2, and disodium octaborate tetrahydrate (DOT). The filament was treated as primer-only, topcoat-only, and combined primer/topcoat application. The combustion performance was evaluated by a cone calorimeter following ISO 5660-1: 2002. The results indicated that in the primer-only coating system, the boric acid/borax/disodium octaborate tetrahydrate composite system reduced total smoke production (TSP) by 11.90%, while the total heat release (THR) of the boric acid/borax/disodium octaborate tetrahydrate/ammonium polyphosphate composite system decreased by 18.83%. In the topcoat-only system, the boric acid/borax single-component system exhibited the optimal comprehensive performance, which the peak value of heat release rate (HRR) and the TSP decreased 13.54% and 8.24%, resp. In the combined primer-topcoat systems, THR reductions of 10.99% and 10.21% were achieved. Notably, nano-SiO2/boric acid/borax exhibited superior smoke suppression performance, with a 14.12% decrease in TSP, attributed to the synergistic physical barrier effect between the silicate network formed by nano-SiO2 and the boron-based glassy protective layer

Effects of differrent boron-based flame retardants on the combustibility of bamboo filaments

In this study, eight types of boron-based flame retardants were performed to evaluate the effects of different boron components on the combustibility of the bamboo filaments. Disodium octaborate tetrahydrate, boric acid/borax, and nano-ZnBO4 were used as the active flame retardant components. Besides, other inorganic flame retardants including nano-SiO2 and ammonium polyphosphate (APP) were also introduced in order to increase the flame retardant of these boron-based components. The combustibility of the bamboo filaments treated with different flame retardants were evaluated by cone calorimeter analysis. The results showed that the flame retardants including the heat release and smoke release resistance of the bamboo filaments with different boron-based components and nano-SiO2 or APP, could be significantly improved, especially, in the samples treated with the compound flame retardant composed of boric acid, borax and nano-SiO2, which was attributed to the synergistic effect of these flame retardant components.