THE EFFECT OF COLORANTS ON THE DEGRADATION PERFORMANCE OF WOOD PLASTIC COMPOSITES

The degradation performance of the colorful wood flour/poly (β-hydroxybutyrate valerate) composites (CWPHBVs) in natural outdoor landfill was investigated by some physical, analytical, and microscopic tests. The mass loss rate of the CWPHBVs within 80 days of degradation shows a growth trend and the mass loss rate decreases by more than 20%. With the increase of degradation time, the bending strength of the CWPHBVs continues to decline, the elastic modulus of the CWPHBVs shows a logarithmic decline trend. After 30 days, the bending strength of the CWPHBVs decreases over 50% and tend to be stable. The colorant has a certain inhibitory effect on the degradation. However, with the shedding of the colorant, the effect of the colorant on the degradation is gradually weakened. The addition of colorants reduces the decomposition rate of PHBV and improves the thermal stability of poplar fibers. However, after 20 days, this effect almost disappears

Effect of Water Absorption on the Mechanical Properties of Silane-Treated Wood Flour Polypropylene Composites

The behavior of the wood flour-polypropylene composites prepared with various contents of untreated and silane-treated wood flour by immersion in water was studied, as well as the effect of the water absorbed by the samples on their mechanical properties. The highest degree of water absorption was observed for the composites containing 30 – 50 mass% alkali pre-treated wood flour. For the materials with 50 mass% untreated, silane-treated and alkali pre-treated wood flour, the water absorption measured was 8.76%, 7.84% and 13.91%, respectively, after 15 days immersion in water. The value of the thickness swelling calculated for the samples prepared with 50 mass% silane-treated wood flour – polypropylene was the lowest – 1.29%. It was proved that the absorption of water molecules results in change of the tensile profile of the thermoplastic polypropylene composites filled with hygroscopic filler.

Study on the structure and properties of poly(3-hydroxybutyrate-co-4-hydroxybutyrate)/ rubber wood fiber composites modified with titanate coupling agent

In this study, the biodegradable composites were prepared from rubber wood fibers (Hevea brasiliensis) and biopolymer poly(3-hydroxybutyrate-co-4-hydroxybutyrate) (P34HB) via hot pressing process, using the titanate as the coupling agent. The morphological, chemical structure, mechanical properties and water absorption (WA) of the composites were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), mechanical properties and WA analysis. Results showed that a new absorption peak of Ti-O-C was formed due to the addition of titanate, indicating that it was successfully grafted on the surface of wood fibers. In addition, the mechanical properties of the composites first increased and then decreased with the increasing of the titanate content. The obvious improvement of WA of composites was attributed to the inclusion of P34HB by titanate modified wood fiber. Moreover, it was also found that the optimal condition of the titanate coupling agent content was 1 wt%.