The effect of combined melamine-resin-colouring agent modification on water related properties of beech wood

Beech wood (Fagus sylvatica L.) was modified with aqueous solutions of methylated N-methylol melamine (NMM) and a metal-complex dye and the water related properties were determined. Wood blocks, treated to the highest weight percent gain (WPG), attained approximately 5 % cell wall bulking and 30 % anti-swelling efficiency (ASE) after ten cycles of water saturation and drying. The metal-complex dye was stably fixed in the resin matrix and was hardly washed out. The equilibrium moisture content of the modified samples related to the dry mass of untreated beech wood (EMCR) was not considerably reduced compared to the EMC of the control. The maximum swelling of the modified samples as a result of vapour sorption was only reduced above 65 % relative humidity compared to the control. Capillary water uptake of wood was significantly reduced by the resin modification. The results indicate the potential of the combined modification to improve the water related properties of wood.

Properties of medium-density fibreboards bonded with dextrin-based wood adhesive

This study focuses on manufacturing of medium density fibreboard (MDF) panels bonded with dextrin-based wood adhesive and crosslinked in situ with various weight ratios of synthetic (e.g., polymeric-methane diphenyl-diisocyanate, pMDI) or bio-based (e.g., glyoxal) crosslinkers. The physical and mechanical properties of the panels were evaluated and compared with those from panels without crosslinker (control). Modulus of rupture (MOR) and internal bond (IB) strength of the MDF panels were considerably increased by increasing the crosslinkers’ content. While, slight improvements were observed in modulus of elasticity (MOE) of the panels as a function of crosslinker type and content. Addition of crosslinkers clearly reduced the thickness swelling (TS) and water absorption (WA) of the panels, whereas, the panels with pMDI showed superior performances than the control and glyoxal added ones within 4 h and 24 h immersion in water. The results indicate the potential of dextrin as wood panel adhesive along with the use of appropriate crosslinkers.