Flame retardance and antibacterial performance of wooden wallpaper treated with composite modifying agent

To improve the flame retardance and antibacterial properties of wooden wallpaper, a composite modifying agent, containing primarily a phosphorus-nitrogen flame retardant (APP/PER/GP), synergistic and smoke suppression agent (OMMT) and silver loaded with nano TiO2 (Ag-TiO2), was prepared and applied to the wooden wallpaper using an ultrasonic immersion method. The combustion performance (including smoke suppression performance), antibacterial activity and the surface micrographs of the flame retardant/antibacterial wooden wallpaper (FRAW) were investigated and characterized using a cone calorimeter test (CCT), antibacterial rate (AT) and inhibition zone, atomic force microscope (AFM), field emission scanning electron microscope (FE-SEM) and energy dispersive spectrometer (EDS). Furthermore, CIE1976 (L* a* b*) color system was used to estimate the surface color change of the FRAW. It was found that the composite modifier distributed on the surface of FRAW with a micrometer, improved the flame retardance of FRAW, but also improved its antibacterial property. In addition, the smoke release behavior of the FRAW indicated that OMMT had good smoke suppression properties. Furthermore, the result of color difference test showed that the flame retardant and antibacterial treatment had little effect on the decorative appeal of the wooden wallpaper.

The synergistic smoke suppression effect of ferric oxide on flame retardant wood-polyurethane composites

Wood flour-polyurethane composites (WPC) with ammonium polyphosphate (APP) and ferric oxide (Fe2O3) were prepared to research the cooperative influence of smoke suppression and fire resistance. By the methods of cone calorimeter test (CCT), smoke density test (SDT), thermogravimetric analysis (TG), limiting oxygen index (LOI), field emission scanning electron microscope (FE-SEM) and Fourier transform infrared spectroscopy (FTIR). Remarkably, Fe2O3 has significant improvement on heat release rate (HRR), total heat release (THR), smoke factor (SF), and total smoke release (TSR) of the APP/WPC.SDT implied that Fe2O3 played a positive role during burning and there is a synergistic effect of smoke suppressing for Fe2O3 on APP/WPC. The LOI results showed that compared with samples without flame retardant, adding Fe2O3 improved the LOI value of WPC. TG indicated that Fe2O3 and APP played an effective role in the course of thermal degradation of WPC. And the SEM and FTIR showed that Fe2O3 and APP played a role in ameliorating the residual carbon structure.