In this study, transparent wood was prepared by deactivating chromophore groups in raw balsa wood, followed by solvent free dehydration and a subsequent vacuum-assisted polymer infiltration. Thermal degradation of transparent wood takes place in two main steps. Optical properties (colorimetry, transmittance) of transparent wood made from balsa wood and acrylic polymers were studied. Highest values of transmittance in the visible part of spectra were achieved by 0.7 mm thick samples at approx. 77%. The dependence of thickness on transmittance showed a linear decrease with increasing thickness of transparent wood. The created material also exhibits absorbing properties in visible and UV spectra.
Since the methods based on the interaction of a relatively low intensity flame on the lignocellulose sample surface often do not allow measuring the heat release rate (HRR), a procedure using oxygen consumption calorimetry was proposed. The method was applied to OSB samples with dimensions of 320 mm x 140 mm x 25 mm placed in a vertical position. During the measurement, in addition to the HRR, the production of smoke, which was significant after stopping the burner, was also monitored. The average net value of HRR at burner outputs of 3 kW, 4 kW and 5 kW was 2.339 kW and the smoke specific extinction area was in the range of 10.88 m2.kg-1 and 13.19 m2.kg-1.
This study deals with the investigation of impact of temperature and ultraviolet (UV) radiation on spruce wood (Picea abies (L.) H. Karst.) and fir wood (Abies alba Mill.) colour changes. Samples of investigated woods species were loaded by temperatures of 110, 130, and 150°C and UV radiation (with 253.7 nm wavelength and 40 W m-2 intensity) during 72, 168, 336 and 672 hours. Colour changes were evaluated in the CIE Lab colour space. The neural network for prediction of both colour coordinates and total colour difference of spruce and fir wood was trained by data regarding exposure conditions (temperature, UV radiation and time) and by obtained results. Coefficient of determination (R2) of the neural network was above 0.99 for training, validation and testing. Average colour coordinates (± standard deviation) of the spruce and fir wood before exposure were L* = 80.08 ± 3.70, a* = 7.55 ± 2.13, b* = 21.56 ± 1.79, L* = 80.46 ± 1.91, a* = 6.84 ± 0.97, and b* = 18.90 ± 1.26, resp. Total colour differences after thermal loading were in the interval from ΔEab* = 3.76 ± 1.95 (spruce wood at 110°C) to ΔEab* = 45.37±1.46 (fir wood at 150°C). Total colour differences of both wood species exposed by UV radiation were approximately in intervals from ΔEab* = 12 to 13 (after 72 h) up to ΔEab* = 16 to 20 (after 168 to 672 h). Obtained results proven that both temperature and UV radiation have significant impact on the colour changes of the investigated woods.
This study is aimed to investigate of an impact of electrical cables installed on Norway spruce (Picea abies (L.) Karst.) wood board surface on main ignition parameters (mainly critical heat flux, ignition temperature, thermal response parameter and thermal inertia). Ignition parameters have been determined by dependence of ignition times (raised to the power of -1, -1/2 and -0.547) on heat flux. Initiation times have been measured for three configurations of spruce wood boards with surface dimensions of 100 x 100 mm ± 1 mm (the first configuration: board without cables on surface, the second configuration: board with three electrical cables on surface – spacing between cables was equal to their diameter and the third configuration: board with five electrical cables – spacing between cables was equal to their diameter) at five heat fluxes (30, 35, 40, 45 and 50 kW·m-2). Obtained results proved that installation of the electrical cables on the spruce wood board surface has a significant impact on the ignition parameters. The critical heat flux (8.5 kW·m-2), apparent thermal inertia 0.20 ± 0.02 kJ2·m-4·K-2·s-1 and ignition temperature 324 ± 105°C of spruce wood board increased up to 18 ± 3 kW·m-2 (critical heat flux), 0.68 ± 0.03 kJ2·m-4·K-2·s-1 (apparent thermal inertia) and 475 ± 27°C (ignition temperature) by the installation of electrical cables on the surface of spruce wood board.
The paper deals with the possibility of floating flooring ignition due to radiant heat. Samples of floating flooring with dimensions of 100 ± 1 mm x 100 ± 1 mm and thickness of 6 mm were thermally loaded by different densities of external heat flux. The flaming combustion was initiated either solely by means of radiant heat, or in combination with electric spark igniter. Cone calorimeter was used for the determination of the critical heat flux. Time to ignition for each sample was recorded and the obtained data were used for the calculation of the critical heat flux density.
The Fischer-Tropsch process is a chemical reaction that enables liquid hydrocarbons to be produced from coal, natural gas, or biomass (e.g. wood). The heat of combustion and effective heat of combustion are important data for fuel used to produce energy. The usefulness of a particular fuel for society is usually evaluated on the basis of the energy returned versus the energy invested (EROI) = energy recovered/energy invested. The subject of the research was the product of a Fischer-Tropsch synthesis from a synthesis gas, which was produced through the liquefaction of sawdust from spruce wood. The synthesis took place in the reactor FIX BED at a temperature of 220 to 350°C and a pressure of 2 to 3 MPa (the hydrogen to carbon monoxide ratio was approximately 2:1). The Fischer-Tropsch fuel that was produced had a heat of combustion of 27.79 M.kg-1, effective heat of combustion 25.14 M.kg-1 and an EROI coefficient of 2.39.
The paper deals with the research of electrical cables embedded in surface grooves of OSBs and its impact on the critical heat flux. An OSB type 3 board (structural board for use in dry or humid environments) and an electrical cable with fire reaction class B2ca have been investigated. Four different configurations of grooves were investigated. The first configuration consisted of an OSB without grooves (control sample). The second configuration consisted of an OSB with a single groove in the centre in which the electrical cable was mounted. In the third and fourth configurations, there were three and five grooves, respectively in which the electrical cables were mounted (the width of the grooves and the spacing between them was 9 mm). The critical heat flux was calculated from the ignition times at five different heat fluxes (30, 35, 40, 45 and 50 kW.m-2) by using a cone calorimeter. The obtained data showed that the OSB without grooves (first configuration) shows the lowest critical heat flux (8.6 kW.m-2) and the lowest standard deviation of ± 0.5 kW.m-2 (lower ignition resistance) compared to the other configurations (critical heat flux in the range from 9 to 10 kW.m-2 and standard deviation from 3.1 to 3.2 kW.m-2).