WOOD RESEARCH Volume 62, Number 1, 2017
Ilyas Deveci, Ergun Baysal, Hilmi Toker, Mehmet Yuksel, and Turkay Turkoglu

Thermal characteristics of oriental beech wood treated with some leaching resistant borates

It was aimed to investigate thermogravimetric analysis (TGA), differential-thermogravimetric (DTG), and differential-thermal analysis (DTA) of Oriental beech (Fagus orientalis L.) wood treated with some leaching resistant borates such as sodium tetraphenylborate (STPB) and phenylboronic acid (PBA). In this study; 0.25, 1.00, and 4.70 % aqueous solutions of borates were prepared. Results of the study indicated that pyrolysis occurred in three stages for STPB and PBA treated Oriental beech wood. Generally, while concentrations of the STPB and PBA increased, Ti and Tmax values of STPB and PBA treated wood specimens decreased. Residual char contents of STPB and PBA treated wood specimens for all concentrations were higher than untreated control specimen.

WOOD RESEARCH Volume 64, Number 5, 2019
Han Que, Yuguo Dong, Haoquan Guo, Xinyu Lu, Xiaojun Zhu, Yimeng Zhang, and Xiaoli Gu

Pyrolytic kinetics of steam exploded lignin by TG/DTG analysis

Steam exploded lignin (SEL) thermal decomposition was investigated by thermogravimetric technique (TG/DTG) within the temperature range from room temperature to 920°C under different heating rates (10, 20, 30, 40, and 50°C. min-1). Little differences in the mass losses with heating rates were observed from TG analysis. It was established that SEL pyrolysis consisted of three main stages: water evaporation (< 200°C); devolatilization of organic volatiles (200-600°C); and char formation (> 600°C). The kinetic processing of non-isothermal TG/DTG data was performed by model-free methods proposed by Flynn-Wall-Ozawa (FWO) and Kissing-Akahira-Sunose (KAS). The average activation energies calculated from FWO and KAS methods are 74.2 kJ. mol-1 and 173.2 kJ. mol-1, respectively. Experimental results showed that values of kinetic parameters from both methods were analogous and could be successfully applied to understand the complex degradation mechanism of SEL. It is also helpful to achieve a better understanding of the devolatilization process of different type of biomass.

WOOD RESEARCH Volume 66, Number 1, 2021
Juraj Jancík, Linda Makovická Osvaldová, and Frank Markert

Thermogravimetric analysis, differential scanning calorimetry and time-to-ignition of wood materials treated with water glass flame retardants

The paper investigates efficiency of silicate flame retardants on wooden fibres (used for production of medium-density fibreboards) and spruce boards. A simultaneous thermal analysis and cone calorimetry were used for the assessment. Specimens were treated with three different types of silicate water glass: sodium silicate, potassium silicate and modified silicate. Along with these, one sample of untreated fibres was tested in order to provide a baseline sample. As a result of the simultaneous thermal analysis, the ability of the treatments to increase the residual amount of biological char in samples during pyrolysis and ability of the flame retardant to be retained in these wood fibres was used to assess the efficiency of each flame retardant on the wood fibres.