Fabrication of superhydrophobic wood surface with a silica/silicone oil complex emulsion
The superhydrophobic wood surface was fabricated in this study by impregnating oven-dry poplar (Populus cathayana Rehd.) samples with a silica/silicone oil complex emulsion (SSOCE), mainly composed of two silicone oils(hydroxy silicone oil and hydrogen silicone oil) and two different sized silica particles (micron and nano scaled, respectively). Different concentrations of the complex emulsion (5%, 10%, 20%, 30% and 40%) were used and their effect on static contact angles (CAs) and surface free energy (SFE) of wood were investigated. The chemical and morphological changes of modified wood surface were characterized by attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS). The superhydrophobic wood surfaces were manifested by the water CA of about 154.8° on the transverse section, 151.3 °on the tangential section and 150.2° on the radial section, respectively. It was confirmed that silicone oilsin the complex emulsion formed a silicon resin filmand uniformly attached on the wood surface, with silica particles in micron and nano scales helped to make the surface rougher.