The effect of combined melamine-resin-colouring agent modification on water related properties of beech wood

Beech wood (Fagus sylvatica L.) was modified with aqueous solutions of methylated N-methylol melamine (NMM) and a metal-complex dye and the water related properties were determined. Wood blocks, treated to the highest weight percent gain (WPG), attained approximately 5 % cell wall bulking and 30 % anti-swelling efficiency (ASE) after ten cycles of water saturation and drying. The metal-complex dye was stably fixed in the resin matrix and was hardly washed out. The equilibrium moisture content of the modified samples related to the dry mass of untreated beech wood (EMCR) was not considerably reduced compared to the EMC of the control. The maximum swelling of the modified samples as a result of vapour sorption was only reduced above 65 % relative humidity compared to the control. Capillary water uptake of wood was significantly reduced by the resin modification. The results indicate the potential of the combined modification to improve the water related properties of wood.

Hydrophobic properties of wood traeted with propolis-silane formulations

The study presents results of hydrophobic properties examination of Scots pine wood treated with a propolis extract and two propolis-silane formulations determined by contact angle analysis and water uptake test. From contact angles data the surface free energy and its shares as well as the work of adhesion were calculated and described in this paper. Treatment with the ethanolic extracts of propolis (EEP) and the propolis-silane formulations a water repellent property of treated wood when compared to control wood. Addition of silicon compounds to the propolis extract caused decreased of the water uptake and increased of the contact angle value of treated wood. The most effective hydrophobic effect was obtained using the impregnation with the formulation based on EEP and organosilanes: vinyltrimethoxysilane (VTMOS) and tetraethyl orthosilicate (TEOS).